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Electrochemistry

Board » Bihar Board » Class 12th » English Medium » Science » Chemistry » Part-1 » Unit 3: Electrochemistry

Objective Questions (MCQs)

Question
Multiple Choice
ID- 12321
BSEB, 2020 (A)

1. In galvanic cell, anode is:

  • (A) Negative electrode
  • (B) Positive electrode
  • (C) Neutral electrode
  • (D) None of these
Multiple Choice
ID- 12322
BSEB, 2019 (C)

2. The cell which involves the conversion of chemical energy into electrical energy is called:

  • (A) Electrolytic cell
  • (B) Galvanic cell
  • (C) Conductivity cell
  • (D) All of these
Multiple Choice
ID- 12323
BSEB, 2019 (C)

3. When flow of electric current in a conductor is through flow of electron then, the conductor is called:

  • (A) Metallic conductor
  • (B) Electrolytic conductor
  • (C) Bad conductor
  • (D) None of these
Multiple Choice
ID- 12324
BSEB, 2013, 2015, 2016 (A)

4. If 96500 coulomb electricity is passed through CuSO4 solution, it will liberate.

  • (A) 63.5 gm of Cu
  • (B) 31.76 gm of Cu
  • (C) 96500 gm of Cu
  • (D) 100 gm of Cu
Multiple Choice
ID- 12325
BSEB, 2013

5. Fused NaCI on electrolysis gives .......... on cathode.

  • (A) Chlorine
  • (B) Sodium
  • (C) Sodium amalgam
  • (D) Hydrogen
Multiple Choice
ID- 12326
BSEB, 2018 (C)

6. In an aqueous solutions hydrogen (H2) will not reduce:

  • (A) Fe3+
  • (B) Cu2+
  • (C) Au2+
  • (D) Ag+
Multiple Choice
ID- 12327

7. Which of the following is a second cell?

  • (A) Leclanche cell
  • (B) Lead storage battery
  • (C) Concentration cell
  • (D) All of these
Multiple Choice
ID- 12328

8. Equilibrium constant K is related to E°cell and not Ecell because:

  • (A) E°cell is easier to measure than Ecell
  • (B) Ecell because zero at equilibrium point but E°cell remains constant under all conditions
  • (C) at a given temperature, Ecell changes hence value of K can't be measured
  • (D) any of the terms Ecell or E°cell can be used
Multiple Choice
ID- 12329

9. Cell reaction is spontaneous, when:

  • (A) E°red is negative
  • (B) ∆G° is negative
  • (C) E°oxid is position
  • (D) ∆G° is positive
Multiple Choice
ID- 12330

10. Molar conductivity of 0.15 M solution of KCI at 298 K, if it's conductivity of 0.0152 S cm–1 will be:

  • (A) 124 Ω–1 cm2 mol–1
  • (B) 204 Ω–1 cm2 mol–1
  • (C) 101 Ω–1 cm2 mol–1
  • (D) 300 Ω–1 cm2 mol–1
Multiple Choice
ID- 12331

11. Electrical conductance though metals is called metallic or electric conductance and is due the movement of electrons. The electronic conductance depends on:

  • (A) the nature and structure of the metal
  • (B) the number of valence electrons per atom
  • (C) change in temperature
  • (D) all of these
Multiple Choice
ID- 12332

12. The specific conductivity of N/10 KCI solution at 20°C is 0.0212 ohm–1 cm–1 and the resistance of the cell containing this solution at 20°C is 55 ohm. The cell constant is:

  • (A) 3.324 cm–1
  • (B) 1.166 cm–1
  • (C) 2.372 cm–1
  • (D) 3.682 cm–1
Multiple Choice
ID- 12333
BSEB, 2016, 2017 (C)

13. Faraday's second law of electrolysis is related to:

  • (A) Atomic number of cation
  • (B) Speed of cation
  • (C) Speed of anion
  • (D) Equivalent weight of electrolyte
Multiple Choice
ID- 12334

14. The molar conductivity is maximum for the solution of concentration:

  • (A) 0.004 M
  • (B) 0.002 M
  • (C) 0.005 M
  • (D) 0.001 M
Multiple Choice
ID- 12335

15. How long would it take to deposit 50 g of Al from an electrolytic cell containing Al2O using a current of 105 ampere?

  • (A) 1.54 h
  • (B) 1.42 h
  • (C) 1.32 h
  • (D) 2.15 h
Multiple Choice
ID- 12336

16. The charger required for reducing 1 mole of MnO4 to Mn2+ is:

  • (A) 1.93 x 105 C
  • (B) 2.895 x 105 C
  • (C) 4.28 x 105 C
  • (D) 4.825 x 105 C
Multiple Choice
ID- 12365

17. How much electricity in terms of Faraday is required to produce 100 g of Ca from molten CaCI2?

  • (A) 1 F
  • (B) 2 F
  • (C) 3 F
  • (D) 5 F
Multiple Choice
ID- 12366

18. If a current 1.5 ampere flows through metallic for 3 hours, then how many electrons would flow through the wire?

  • (A) 2.25 x 1022 electrons
  • (B) 1.13 x 1023 electrons
  • (C) 1.01 x 1023 electrons
  • (D) 4.5 x 1023 electrons
Multiple Choice
ID- 12367
BSEB, 2021 (A)

19. How many charge is required for reduction of 1 mole of Al3+ to Al?

  • (A) 3.0 x 105C
  • (B) 28.95 x 105C
  • (C) 289.5 x 105C
  • (D) 2895 x 105C
Multiple Choice
ID- 12368
BSEB, 2021 (A)

20. The standard reduction potential values of elements A, B and C are + 0.68 V, –2.50 V and –0.50 V respectively. The order of their reducing power is:

  • (A) A > B > C
  • (B) A > C > B
  • (C) C > B > A
  • (D) B > C > A
Multiple Choice
ID- 12369

21. How much metal will be deposited when a current on 12 ampere with 75% efficiency is passed through the cell for 3 h? (Given : Z = 4 x 10–4)

  • (A) 32.4 g
  • (B) 38.8 g
  • (C) 36.0 g
  • (D) 22.4 g
Multiple Choice
ID- 12370
BSEB, 2018 (C)

22. Which has the maximum standard oxidation potential?

  • (A) Zn
  • (B) Cu
  • (C) Ag
  • (D) Mg
Multiple Choice
ID- 12371

23. Which of the following statements is not correct about an inert electrode in a cell?

  • (A) It does not participate in the cell reaction.
  • (B) It provides surface either for oxidation or for reduction reaction.
  • (C) It provides surface for conduction of electrons.
  • (D) It provides surface for redox reaction.
Multiple Choice
ID- 12372

24. An electrochemical cell can behave like an electrolytic cell when .......... .

  • (A) Ecell = 0
  • (B) Ecell > Eext
  • (C) Eext > Ecell
  • (D) Ecell = Eext
Multiple Choice
ID- 12373

25. Which of the statements about solutions of electrolytes is not correct?

  • (A) Conductivity of solution depends upon size of ions.
  • (B) Conductivity depends upon viscosity of solution.
  • (C) Conductivity does not depend upon salvation of ions present in solution.
  • (D) Conductivity of solution increases with temperature.
Multiple Choice
ID- 12374
BSEB, 2021 (A)

26. The electromotive force (EMF) of the cell for the cell reaction at equilibrium state is:

  • (A) positive
  • (B) zero
  • (C) negative
  • (D) none of these
Multiple Choice
ID- 12375

27. The quantity of charge required to obtain one mole of aluminium from Al2O3 is .......... .

  • (A) 1 F
  • (B) 6 F
  • (C) 3 F
  • (D) 2 F
Multiple Choice
ID- 12376
BSEB, 2019 (A)

28. One Faraday electricity equal to how much Coulombs?

  • (A) 96550
  • (B) 96500
  • (C) 96000
  • (D) 95500
Multiple Choice
ID- 12377

29. Why charging the lead storage battery .......... .

  • (A) PbSO4 anode is reduced to Pb
  • (B) PbSO4 cathode is reduced to Pb
  • (C) PbSO4 cathode os oxidised to Pb
  • (D) PbSO4 anode is oxidised to PbO2
Multiple Choice
ID- 12378
BSEB, 2021 (A)

30. Zn (s) | Zn2+ (aq) || Cu2+ (aq) | Cu (s) is:

  • (A) Weston cell
  • (B) Daniel cell
  • (C) Calomel cell
  • (D) None of these
Multiple Choice
ID- 12379
BSEB, 2017 (A)

31. When one faraday of electric current is passed, the mass deposited, is equal to:

  • (A) One gram equivalent
  • (B) One gram mole
  • (C) electrochemical equivalent
  • (D) Half gram equivalent
Multiple Choice
ID- 12380
BSEB, 2016 (C)

32. The electrode thought which electrons enter into electrolytic solution is:

  • (A) Cathode
  • (B) Anode
  • (C) May be anode cathode
  • (D) None
Multiple Choice
ID- 12381
BSEB, 2018 (A)

33. A dilute aqueous solution of sodium fluoride is electrolysed, the products at the anode and cathode are:

  • (A) F2, Na
  • (B) F2, H2
  • (C) O2, Na
  • (D) O2, H2
Multiple Choice
ID- 12382
BSEB, 2018 (A)

34. Equivalent conductance of saturated BaSO4 is 400 ohm–1 cm2 eqvt–1 and specific conductance is 8 x 10–5 ohm–1 cm–1. The Ksp of BaSO4 is:

  • (A) 4 x 10–8 M2
  • (B) 10–8 M2
  • (C) 2 x 10–4 M2
  • (D) 10–4 M2